全文获取类型
收费全文 | 5156篇 |
免费 | 404篇 |
国内免费 | 1193篇 |
专业分类
安全科学 | 280篇 |
废物处理 | 719篇 |
环保管理 | 982篇 |
综合类 | 3217篇 |
基础理论 | 434篇 |
环境理论 | 2篇 |
污染及防治 | 768篇 |
评价与监测 | 231篇 |
社会与环境 | 111篇 |
灾害及防治 | 9篇 |
出版年
2023年 | 47篇 |
2022年 | 91篇 |
2021年 | 119篇 |
2020年 | 149篇 |
2019年 | 103篇 |
2018年 | 120篇 |
2017年 | 140篇 |
2016年 | 206篇 |
2015年 | 211篇 |
2014年 | 430篇 |
2013年 | 442篇 |
2012年 | 437篇 |
2011年 | 427篇 |
2010年 | 289篇 |
2009年 | 345篇 |
2008年 | 304篇 |
2007年 | 357篇 |
2006年 | 404篇 |
2005年 | 297篇 |
2004年 | 230篇 |
2003年 | 289篇 |
2002年 | 224篇 |
2001年 | 176篇 |
2000年 | 196篇 |
1999年 | 143篇 |
1998年 | 113篇 |
1997年 | 76篇 |
1996年 | 83篇 |
1995年 | 77篇 |
1994年 | 59篇 |
1993年 | 45篇 |
1992年 | 32篇 |
1991年 | 15篇 |
1990年 | 12篇 |
1989年 | 4篇 |
1988年 | 2篇 |
1987年 | 8篇 |
1986年 | 3篇 |
1984年 | 4篇 |
1983年 | 3篇 |
1982年 | 4篇 |
1981年 | 5篇 |
1980年 | 7篇 |
1979年 | 6篇 |
1978年 | 2篇 |
1977年 | 4篇 |
1976年 | 2篇 |
1973年 | 3篇 |
1971年 | 3篇 |
1970年 | 1篇 |
排序方式: 共有6753条查询结果,搜索用时 625 毫秒
1.
采用大肠杆菌吸附-化学还原法,以大肠杆菌(ECCs)为模板、十六烷基三甲基溴化铵为保护剂、抗坏血酸为还原剂,由废含金催化剂制备金纳米线(AuNWs)。采用XRD,SEM,TEM等技术对AuNWs进行表征。研究了AuNWs对罗丹明6G(R6G)和4-巯基苯甲酸(4-MBA)的拉曼散射信号的增强效果。实验结果表明:在制备过程中加入微生物ECCs,可使金回收率提高约20百分点;当溶液pH小于4时,反应2 h后,有大量呈线状的AuNWs聚集沉降,金回收率可达99%1以上。表征结果显示,AuNWs呈多晶结构,晶格间距为0.23 nm。表面增强拉曼散射分析表明,AuNWs对R6G和4-MBA具有良好的拉曼光谱增强性能。 相似文献
2.
采用含有二乙二醇(DEG)和乙醇胺(ETA)的双组分解交联剂降解废旧硬质聚氨酯泡沫塑料(PU硬泡),并利用降解得到的低聚物多元醇与木质素复合制备出性能增强的再生PU硬泡。通过对制备的再生PU硬泡的红外光谱、密度、吸水率、抗压强度、热稳定性、导热系数、热重曲线等进行分析测试,考察m(DEG)∶m(ETA)对再生PU硬泡性能的影响。实验结果表明:m(DEG)∶m(ETA)=1∶3时废旧PU硬泡的降解效果最好;木质素加入量为2.0%(w)时再生PU硬泡的密度低、抗压强度高、保温性能良好,达到国家标准《建筑绝热用硬质聚氨酯泡沫塑料》(GB/T 21558—2008)的品质要求。 相似文献
3.
为了实现密相塔半干法脱硫工艺的精确加湿进一步提高系统脱硫效率,利用推导出的传热传质计算方法,得到烟气温度降低和加水量的关系.结合3组密相塔半干法工程实际数据,发现理论计算值和实测值误差区间仅为2.9% ~5.4%.通过选取河北某钢厂210 m2烧结烟气密相塔半干法脱硫项目实际在线检测数据,发现循环脱硫灰含湿量为3%的系统脱硫效率整体高于含湿量为5%和4%的样品,最大值达93.56%.通过粒度分析、扫描电镜、X射线衍射及差热-热重对2种不同含湿量的循环脱硫灰进行表征,结果表明,含湿量为3%的循环脱硫灰较含湿量为5%的样品粒径小、比表面积大,无团聚现象,物相分析还证实相对于含湿量为5%样品,其Ca(OH)2和结晶水含量少,几乎都是CaSO4和CaS03干态物质,因此脱硫反应进行彻底,脱硫效率较高. 相似文献
4.
5.
San Vicente Bay is a coastal shallow embayment in Central Chile with multiple uses, one of which is receiving wastewater from
industrial fisheries, steel mill effluents, and domestic sewage. A simulation model was developed and applied to dissolved
oxygen consumption by organic residues released into this embayment. Three compartments were established as function of: depth,
circulation and outfall location. The model compartments had different volumes, and their oxygen saturation value was used
as baseline. The parameters: (a) BOD5 of the industrial and urban effluents, (b) oxygen demand by organic sediments, (c) respiration, (d) photosynthesis and (e)
re-aeration were included in the model. Iteration results of the model showed severe alterations in Compartment 1, with a
decrease of 65% in the oxygen below saturation. Compartment 2 showed a small decline (10%) and compartment 3 did not show
apparent changes in oxygen values. Measures recommended for remediation were to decrease the BOD5 loading by 30% in the affected sector. Iteration of the model for 200 h following recommendations derived from the preceding
results produced an increase in saturation of 60% (5 ml O2 L−1), which suggested an improvement of the environmental conditions. 相似文献
6.
The feasibility of using U.K. coal-fired power station waste materials for artificial reef production is being examined. in June, 1989, an experimental artificial reef was constructed in Poole Bay, off the central south coast of the U.K., using three different mixtures of pulverised fuel ash (PFA), flue gas desulphurisation (FGD) gypsum and slurry, stabilized with cement and formed into blocks. Fifty tonnes of 40 × 20 × 20 cm blocks were formed into eight conical reef units replicating three different PFA/gypsum mixtures and one concrete control. the reef structure is 10m below chart datum on a flat sandy sea-bed.
Combustion of coal concentrates the heavy metal content in the resultant ash. the purpose of stabilization of the ash as blocks is twofold: to immobilize heavy metals (or other components) and to provide hard substratum for the attachment of organisms. to examine the effectiveness of this stabilization and hence the environmental compatibility of the block materials, heavy metal (Cd, Cr, Cu, Pb, Mn, Ni, Zn) content of the blocks has been monitored routinely over two years, to determine leaching rates. Sectional profiles indicate partial replacement of calcium content by magnesium. Associated with this there has also been some redistribution of heavy metals. Only in the case of cadmium has there been a detectable loss from the surface of blocks. Chromium and manganese concentrations appear to have increased. the metal content of the reef epibiota (including ascidians, Ascidia mentula; hydroids, Halecium spp.; bryozoans, Bugula spp. and red algae) growing on the ash blocks has been compared to that of epibiota attached to the concrete controls and surrounding sea-bed. to date no evidence of excess bioaccumulation of metals has been detected.
The physical integrity of the ash reef blocks has been maintained. There is evidence that the blocks are increasing in compressive strength.
An indication of the fishery enhancement potential of the experimental structure is given by the presence of eight commercially fished species (crustaceans and molluscs) including lobsters (Homarus gammarus). 相似文献
Combustion of coal concentrates the heavy metal content in the resultant ash. the purpose of stabilization of the ash as blocks is twofold: to immobilize heavy metals (or other components) and to provide hard substratum for the attachment of organisms. to examine the effectiveness of this stabilization and hence the environmental compatibility of the block materials, heavy metal (Cd, Cr, Cu, Pb, Mn, Ni, Zn) content of the blocks has been monitored routinely over two years, to determine leaching rates. Sectional profiles indicate partial replacement of calcium content by magnesium. Associated with this there has also been some redistribution of heavy metals. Only in the case of cadmium has there been a detectable loss from the surface of blocks. Chromium and manganese concentrations appear to have increased. the metal content of the reef epibiota (including ascidians, Ascidia mentula; hydroids, Halecium spp.; bryozoans, Bugula spp. and red algae) growing on the ash blocks has been compared to that of epibiota attached to the concrete controls and surrounding sea-bed. to date no evidence of excess bioaccumulation of metals has been detected.
The physical integrity of the ash reef blocks has been maintained. There is evidence that the blocks are increasing in compressive strength.
An indication of the fishery enhancement potential of the experimental structure is given by the presence of eight commercially fished species (crustaceans and molluscs) including lobsters (Homarus gammarus). 相似文献
7.
对安全评价方法在危险废物处置建设项目环境风险评价中的运用进行初步探索。主要用"工艺过程风险因素分析表"对工艺过程潜在风险性识别;用蒙德法进行源项分析;用池火灾模型、蒸气云爆炸伤害模型对易燃、易爆物质的火灾、爆炸等重大事故后果进行计算,得出人员的伤亡半径和财产损失半径等参数,以便于判断风险的可接受水平。分析结果表明:采用安全评价方法对危险废物处置建设项目进行环境风险评价是适用的、可行的。 相似文献
8.
9.
重量法测定含动、植物油和矿物油废水应注意的问题 总被引:4,自引:0,他引:4
废水监测中,用重量法测定污(废)水中的动、植物油和矿物油是常用方法之一。为了保证测试结果的准确性,减少误差,提高分析测试质量,作者以多年的实践经验结合塔里木油田采油厂生产污水和餐饮行业生活废水的测定,对测定两种不同含油类废水应注意的问题进行探讨。供同行在实际工作中参考。 相似文献
10.
基于不同废污泥源的短程反硝化快速启动及稳定性 总被引:1,自引:1,他引:0
为探究不同废污泥源快速启动短程反硝化和实现稳定NO_2~--N积累的可行性,在3个完全相同的SBR反应器(S1、S2和S3)分别接种:实验室城市污水反硝化除磷系统排泥、城市污水厂剩余污泥及河涌底泥,比较其短程反硝化启动快慢和NO_2~--N积累特性,考察系统短程反硝化活性和NO_3~--N→NO_2~--N转化性能,并从微生物学角度分析反应器功能菌群特征.结果表明,在乙酸钠为唯一碳源、高碱度和适宜COD/NO_3~--N比进水条件下,3个SBR短程反硝化反应器在短时间内均能够成功启动,系统平均NO_3~--N→NO_2~--N转化率为S1 S2 S3(75. 92% 73. 36% 69. 90%).同时发现持续低温条件下S1和S2呈现不同程度的短程反硝化性能恶化趋势,但S3能够稳定维持良好NO_2~--N积累性能.微生物高通量测序表明,变形菌门和拟杆菌门居PD系统主导地位,3个短程反硝化反应器NO_2~--N积累关键功能菌属Thauera属丰度差异明显:S3 S1 S2(25. 09% 4. 71% 3. 60%),表明S3具备稳定高效的NO_2~--N积累性能,同时高丰度Thauera属可能是维持低温短程反硝化活性的重要原因. 相似文献